a. Pb3(PO4)2 ----------> 3Pb+2 +
2PO43-
                                         Â
3s      2s
  Â
Ksp          =
[Pb+2]3[PO43-]2
    1*10-54   =
(3s)3 *(2s)2
                  Â
= 108s5
s5Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â
= 1*10-54/108
                  Â
= 0.0926*10-55
s                Â
= 4.5*10-12 M
solubility of Pb3(PO4)2 is 4.5*10-12 M
b.          Â
Hg2Br2 ---------> Hg22+ +
2Br-
                                       Â
0Â Â Â Â Â Â Â Â Â Â
0.3
                                      Â
s         Â
0.3+2s
        Â
Ksp   =
[Hg22+][Br-]2
         Â
6.4*10-23Â Â = s*(0.3+2s)2
            Â
s           Â
= 1.4*10-17
due to commom ion effect solubilities are different in water and
inCaBr2.
        Â