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Consider the Russell- Saunders coupling scheme for two non-equivalent electrons in an excited 2p1 3d1 configuration....

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Chemistry

Consider the Russell- Saunders coupling scheme for twonon-equivalent electrons in an excited 2p1 3d1 configuration. Forall parts (a) to (c) give your reasoning:

(a) Show that strong coupling between orbital angular momenta (ℓℓ coupling) gives rise to P, D and F terms with L magnitudes of2½ħ, 6½ħ and 12½ħ.

(b) If coupling between spin momenta (s-s coupling) isconsidered in addition to â„“ â„“ coupling, what six terms arise?

(c) If coupling between the orbit and spin angular momenta isalso considered (LS coupling), how many terms arise?

Answer & Explanation Solved by verified expert
4.1 Ratings (604 Votes)
Two nonequivalent electrons in an excited 2p1 3d1 configurationa coupling 2p13d1 values of    See Answer
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