Draw and label crystal field splitting diagrams (including
orbital labels) for the following complexes. Calculate he...
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Chemistry
Draw and label crystal field splitting diagrams (includingorbital labels) for the following complexes. Calculate he ligandfield stabilization energy as a factor of Delta for eachcomplex.
a. [Co(OH2)6]2+
b. [RH(NH3)6]2+
c. [NiCl4]2-
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First of all calculate the oxidation state of central atomAssume the oxidation state to be x for central metal and add thecharge of all other atoms present in complex This sum is equal tothe charge present present on the complex If no charge is presentthen sum is equal to zeroIn first complex central metal atom is cobalt 6 H2Oligands are attached to the complex So it is an octahedralcomplex In octahedral complex when ligands approach metal atomthe five degenerate d orbitals split into two sets namelyt2g and eg t2g is a triplydegenerate orbital and is of low energy whereas eg isdoubly degenerate orbital and is of high energy t2gorbital is lowered by 04
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