For the reaction       A(g) + B(g) + C(g)  \"D(g)    the following data wereobtained at 25°C.
Exp’t | Initial [A] (M) | Initial [B] (M) | Initial [C] (M) | Initial Rate (mole∙L–1s–1) |
1 | 0.0500 | 0.0500 | 0.0100 | 6.25 x 10–3 |
2 | 0.1000 | 0.0500 | 0.0100 | 1.25 x 10–2 |
3 | 0.1000 | 0.1000 | 0.0100 | 5.00 x 10–2 |
4 | 0.0500 | 0.0500 | 0.0200 | 6.25 x 10–3 |
5 | 0.2000 | 0.3000 | 0.3000 | ????? |
Which choice gives correct kinetics information for thisreaction?   Which choice is closest to the rateconstant for this reaction?  Which choice is closest tothe missing initial rate for Exp’t 5?
| 1st-order wrt A; 2nd-overall    k = 50.0 Lmol–1s–1    0.00400 mol∙L-1s-1    |
| 1st-order wrt A; 1st-order wrtB      k = 2.5 Lmol–1s–1    0.200 mol2L–2s–1    |
| 2nd-order wrt B; 3rd-order overall  k = 50.0 L2mol–2s–1    0.900 mol∙L-1s-1      |
| 2nd-order wrt B; 1st-order wrt C    k = 25 L2mol–2s–1    0.200 mol∙L-1s-1   |
