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Given the following reaction and thermodynamic data, what is areccomended temperature for a 1 L pilot scale reactor and how long(time) does it take for the reaction to take place?
CH3OCH2CH2CH2OCH2NH2 -> CH3OCH2CH2CH2OH + CH2=NH
Species | CH3OCH2CH2CH2OCH2NH2 | CH3OCH2CH2CH2OH | CH2NH |
Hf (Kcal/mol) | -91.15 | -92.23 | 19.75 |
S (cal/mol/K) | 118.08 | 97.18 | 54.18 |
300 | 39.13 | 29.37 | 8.92 |
400 | 48.84 | 36.69 | 10.39 |
500 | 56.65 | 42.77 | 11.99 |
600 | 63.34 | 48.03 | 13.47 |
800 | 74.69 | 56.74 | 15.95 |
1000 | 82.87 | 62.98 | 17.87 |
1500 | 0 | 0 | 21.02 |
ΔHrxn (Kcal/mol) | ΔSrxn (cal/mol/K) | ΔGrxn (Kcal/mol) | Kp |
| | | |
| | | |
18.67 | 33.28 | 8.69E+03 | 0.985534268 |
18.494 | 32.77367955 | 5.38E+03 | 0.993248201 |
18.292 | 32.31453957 | 2.13E+03 | 0.99785361 |
18.118 | 32.00460919 | -1.08E+03 | 1.0009103 |
17.67 | 31.31834149 | -7.38E+03 | 1.004656425 |
17.256 | 30.84797494 | -1.36E+04 | 1.0068639 |
43.894 | 67.11038492 | -5.68E+04 | 1.019230233 |
Kc | A-forward (sec^-1) | Ea(Kcal/mol) | K-forward (sec^-1) |
| | | |
| | | |
0.001653304 | 2.10611E+14 | 53.09 | 4.40801E-25 |
0.001249683 | 2.80815E+14 | 52.914 | 3.42895E-15 |
0.001004382 | 3.51018E+14 | 52.712 | 3.18437E-09 |
0.000839549 | 4.21222E+14 | 52.538 | 3.06178E-05 |
0.000632018 | 5.61629E+14 | 52.09 | 3.295681283 |
0.000506726 | 7.02037E+14 | 51.676 | 3561.584427 |
0.000341966 | 1.05305E+15 | 78.314 | 4084.744896 |
Delta S+c (cal/mol/K) | A-backward (sec^-1) | K-backward (sec^-1) |
| | |
| | |
-24.11856204 | 45429261.35 | 9.50818E-32 |
-23.54895154 | 59940560.67 | 7.31917E-22 |
-23.10712731 | 74049093.99 | 6.7176E-16 |
-22.74613063 | 87957142.2 | 6.39344E-12 |
-22.17652012 | 114260467 | 6.70489E-07 |
-21.73469589 | 139369642.5 | 0.000707053 |
-20.93187498 | 531011737.2 | 0.002059767 |
