Much like the CO ligands, cyanide (CN-) ligands have
IR stretching frequencies that are distinctive and...
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Chemistry
Much like the CO ligands, cyanide (CN-) ligands haveIR stretching frequencies that are distinctive and therefore oftenparticularly useful. Consult an appropriate character table, andgive a reducible representation for the cyanide stretchingvibrations in the square-planar tetracyanoplatinate(II) ion,Pt(CN)42-.
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Answer CN is isoelectronic with CO and NO Both CO and CNcoordinate to the metal atom through carbon The free CN ion hasa stretching frequency of 2080 cm1 in
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