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The third order rate coefficient for: O + O2 + M   -> O3 + M is given by...

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Chemistry

The third order rate coefficient for:

O + O2 + M   -> O3 +M

is given by the expression: k = 6.0x10-34*(T/300)-2.4 cm6 molecule-2s-1

This reaction is in the low pressure, i.e. termolecular,limit under all atmospheric conditions.

1) Find the effective bimolecular rate at 220K and apressure of 50 mbar

2) An O2 molecule undergoes photolysis givingO3P

Find the pseudo-first order rate of O3formation at 220K and a pressure of 50 mbar.

What is the lifetime of O3P at 220K and apressure of 50 mbar.

Answer & Explanation Solved by verified expert
3.8 Ratings (545 Votes)
1 A bimolecular reaction involves the collision of tworeactants A and B to yield two products C and D The collisionproduces an activated complex AB which decomposes rapidly eitherto the original reactants A and B or to the products C and D Thereaction is writtenAB C    See Answer
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